Reactivity of the parent amido complexes of iridium with olefins: C–NH2 bond formation versus C

Reactivity of the parent amido complexes of iridium with olefins: C–NH2 bond formation versus C–H activation

Published:2017 Issue:34 Volume:46 Page:11459-11468
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Mena Inmaculada¹²³⁴,García-Orduña Pilar¹²³⁴^ORCID,Polo Víctor⁵⁶³⁴^ORCID,Lahoz Fernando J.¹²³⁴^ORCID,Casado Miguel A.¹²³⁴^ORCID,Oro Luis A.¹²³⁴⁷^ORCID

Affiliation:

1. Instituto de Síntesis Química y Catálisis Homogénea ISQCH

2. Universidad de Zaragoza-CSIC

3. Zaragoza

4. Spain

5. Departamento de Química Física e Instituto de Biocomputación y Física de Sistemas Complejos (BIFI)

6. Universidad de Zaragoza

7. Center for Refining & Petrochemicals

Abstract

Amido-bridged iridium diolefin complexes are split into terminal amido species in the presence of bis(phosphanes), which evolve by forming a C–NH₂ bond or by extrusion of ammonia depending on the nature of the diene.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT01924F

Reference66 articles.

1. Oxidative Addition of NH3 to a Transition-Metal Complex: A Key Step for the Metal-Mediated Derivatization of Ammonia?

2. Advances in selective activation and application of ammonia in homogeneous catalysis

3. Catalytic Organometallic Reactions of Ammonia

4. Synthetic Uses of Ammonia in Transition-Metal Catalysis

5. Oxidative Addition of Ammonia to Form a Stable Monomeric Amido Hydride Complex

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