Synthesis, structure and evaluation of spectral, luminescent and optoelectronic properties of Zn(ii) hexafluoroacetylacetonate complexes of triphenodioxazines

Author:

Ivakhnenko Eugeny P.1ORCID,Makarova Nadezhda I.1,Kislitsin Sergey E.1,Knyazev Pavel A.1ORCID,Starikov Andrey G.1,Demidov Oleg P.2ORCID,Borodkin Gennady S.1ORCID,Minkin Vladimir I.1ORCID

Affiliation:

1. Institute of Physical and Organic Chemistry, Southern Federal University, 194/2 Stachki St., 344090, Rostov-on-Don, Russian Federation

2. North Caucasus Federal University, 1 Pushkin st., 355017, Stavropol, Russian Federation

Abstract

The synthesis of 1 : 1 and 1 : 2 complexes of Zn(ii) hexafluoroacetylacetonate with sterically crowded triphenodioxazines (TPDO) is described, and the compounds are characterized using single-crystal X-ray crystallography, NMR, and IR spectroscopy.

Funder

Russian Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

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