A two step protocol for the synthesis of highly substituted benzobicyclo[2.2.2]octadienone derivatives from 2-methoxyphenols-Reference-Cited by-同舟云学术

A two step protocol for the synthesis of highly substituted benzobicyclo[2.2.2]octadienone derivatives from 2-methoxyphenols

Published:2015 Issue:11 Volume:5 Page:8050-8055
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Chittimalla Santhosh Kumar¹²³⁴,Bandi Chennakesavulu¹²³⁴,Putturu Sireesha¹²³⁴

Affiliation:

1. Medicinal Chemistry Department

2. AMRI Singapore Research Centre

3. Singapore 117525

4. Singapore

Abstract

A rapid process for the synthesis of functionally rich benzobicyclo[2.2.2]octadienone derivatives has been realized through oxidative dimerization of commercially/readily available 2-methoxyphenols followed by an aromatization sequence.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/RA/C4RA14219E

Reference54 articles.

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3. Rearrangement of a bicyclo[2.2.2]octadienol to a dihydropentalene

4. Wagner-Meerwein rearrangements in the solvolyses of benzobicyclo[2.2.2]octenyl and -octadienyl brosylates and nuclear magnetic resonance spectra of the benzobicyclo[3.2.1]octadiene and benzo[3,4]tricyclo[3.2.1.02,7]octene systems

5. Bridged Polycyclic Compounds. XXIII. Some Carbonium Ion Reactions in Dibenzobicyclo[3.2.1]-octadiene Systems

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