Investigating the mechanism of phosphorene nanoribbon synthesis by discharging black phosphorus intercalation compounds

Author:

Shutt Rebecca R. C.1ORCID,Aw Eva S. Y.1ORCID,Liu Qili2,Berry-Gair Jasper2,Lancaster Hector J.1ORCID,Said Samia3ORCID,Miller Thomas S.3ORCID,Corà Furio2ORCID,Howard Christopher A.1ORCID,Clancy Adam J.2ORCID

Affiliation:

1. Department of Physics and Astronomy, University College London, London, WC1E 6BT, UK

2. Department of Chemistry, University College London, London, WC1E 0AJ, UK

3. Electrochemical Innovation Laboratory, Department of Chemical Engineering, University College London, Gower Street, London, WC1E 6BT, UK

Abstract

Phosphorene nanoribbons can be synthesised in by intercalation of black phosphorus with Li followed by dissolution in amides. Our result suggest that the first step does not cut the sheets to ribbons, indicating they are cut by solvent interactions.

Funder

Engineering and Physical Sciences Research Council

Royal Society

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science

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