Syntheses and characterization of phosphonates and diphosphonates of molybdenum, A4[(MoO3)5(O3PR)2]·xH2O, A2[Mo2O5(O3PR)2] and A2[Mo2O5(O3P-R-PO3)] (A = K, Rb, Cs, Tl, NH4)-Reference-Cited by-同舟云学术

Syntheses and characterization of phosphonates and diphosphonates of molybdenum, A4[(MoO3)5(O3PR)2]·xH2O, A2[Mo2O5(O3PR)2] and A2[Mo2O5(O3P-R-PO3)] (A = K, Rb, Cs, Tl, NH4)

Published:2017 Issue:46 Volume:46 Page:16102-16112
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Elias Jesu Packiam D.¹²³⁴^ORCID,Vidyasagar Kanamaluru¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. Indian Institute of Technology Madras

3. Chennai – 600036

4. India

Abstract

Cs₄[(MoO₃)₅(O₃PPh)₂]·6H₂O and K_1.5(H₃O)_0.5[Mo₂O₅(O₃PPh)₂] are molecular and non-molecular phenylphosphonates of molybdenum that contain discrete [(MoO₃)₅(O₃PPh)₂]⁴⁻ and layered [Mo₂O₅(O₃PPh)₂]²⁻ anions respectively.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT03012F

Reference77 articles.

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2. Hybrid Inorganic–Organic Solids: An Emerging Class of Nanoporous Catalysts

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4. Open-Framework Inorganic Materials

5. Metal–organic framework materials as catalysts

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