An imidazolium-modified chiral rhodium/diamine-functionalized periodic mesoporous organosilica for asymmetric transfer hydrogenation of α-haloketones and benzils in aqueous medium
Author:
Affiliation:
1. Key Laboratory of Resource Chemistry of Ministry of Education
2. Shanghai Key Laboratory of Rare Earth Functional Materials
3. Shanghai Normal University
4. Shanghai
5. China
Abstract
An imidazolium-modified chiral rhodium/diamine-functionalized periodic mesoporous organosilica is developed, which greatly promotes asymmetric transfer hydrogenation of α-haloketones and benzils in aqueous medium.
Publisher
Royal Society of Chemistry (RSC)
Subject
Pollution,Environmental Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2016/GC/C6GC01589A
Reference77 articles.
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4. Asymmetric hydrosilylation, transfer hydrogenation and hydrogenation of ketones catalyzed by iridium complexes
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