High-pressure synthesis and crystal structures of molybdenum nitride Mo3N5 with anisotropic compressibility by a nitrogen dimer

Author:

Sasaki Takuya1ORCID,Yamamoto Takuro2,Asano Shuto1ORCID,Niwa Ken1ORCID,Hasegawa Masashi1

Affiliation:

1. Department of Materials Physics, Graduate School of Engineering, Nagoya University, Furo-cho, Chikusa-ku, Nagoya, Aichi 464-8603, Japan

2. Department of Crystalline Materials Science, Graduate School of Engineering, Nagoya University, Furo-cho, Chikusa-ku, Nagoya, Aichi 464-8603, Japan

Abstract

Molybdenum nitride Mo3N5 with higher coordinates of molybdenum sites and an N–N dimer was synthesized under a high pressure of above 45 GPa.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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