Spin-chemical effects on intramolecular photoinduced charge transfer reactions in bisphenanthroline copper(i)-viologen dyad assemblies
Author:
Affiliation:
1. Department of Chemistry
2. Colorado State University
3. Fort Collins
4. USA
5. Max Planck Institute for Chemical Energy Conversion
6. D-45470 Mülheim an der Ruhr
7. Germany
8. University of Konstanz
9. Konstanz
Abstract
Quantum chemical calculations and laser flash spectroscopy probe spin-dynamics of the photoinduced electron transfer mechanism in two donor–acceptor bisphenanthrolinecopper(i) species, marking the influence of spin on solar energy conversion schemes.
Funder
U.S. Department of Energy
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2020/SC/D0SC00830C
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3. Cuprous Phenanthroline MLCT Chromophore Featuring Synthetically Tailored Photophysics
4. K. Kalyanasundaram , Photochemistry of polypyridine and porphyrin complexes , Academic Press , London; San Diego , 1992
5. MLCT excited states of cuprous bis-phenanthroline coordination compounds
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