The crystal structure and characterization of a co-product in the synthesis of a Schiff base give evidence of its zwitterionic nature in the solid state-Reference-Cited by-同舟云学术

The crystal structure and characterization of a co-product in the synthesis of a Schiff base give evidence of its zwitterionic nature in the solid state

Published:2022 Issue: Volume: Page:
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Rodríguez M. R.¹^ORCID,Espino G. A.²^ORCID,Piro O. E.³^ORCID,Echeverría G. A.³^ORCID,Parajón-Costa B. S.¹^ORCID,González-Baró A. C.¹^ORCID

Affiliation:

1. CEQUINOR (CONICET-CCT La Plata, UNLP), Bvd. 120 N°1465, 1900 La Plata, Argentina

2. Departamento de Química, Universidad de Burgos, Pza. Misael Bañuelos s/n, E-09001 Burgos, Spain

3. IFLP (CONICET-CCT La Plata, UNLP), CC 67, B1900AVV, La Plata, Argentina

Abstract

The zwitterionic form of a Schiff base in the solid state was found by the structural characterization of a coproduct and a mechanistic proposal of its formation.

Funder

Consejo Nacional de Investigaciones Científicas y Técnicas

Universidad Nacional de La Plata

European Regional Development Fund

Consejería de Educación, Junta de Castilla y León

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/NJ/D1NJ04537G

Reference24 articles.

1. Structure, tautomerism, spectroscopic and DFT study of o-vanillin derived Schiff bases containing thiophene ring

2. Schiff bases derived from hydroxyaryl aldehydes: molecular and crystal structure, tautomerism, quinoid effect, coordination compounds

3. A structural, spectroscopic and theoretical study of an o-vanillin Schiff base derivative involved in enol-imine and keto-amine tautomerism

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