Deep in blue with green chemistry: influence of solvent and chain length on the behaviour of N- and N,N′- alkyl indigo derivatives

Author:

Pinheiro Daniela12345ORCID,Pineiro Marta12345ORCID,Galvão Adelino M.678910,Seixas de Melo J. Sérgio12345ORCID

Affiliation:

1. University of Coimbra

2. CQC

3. Department of Chemistry

4. 3004-535 Coimbra

5. Portugal

6. Centro de Química Estrutural

7. Departamento de Engenharia Química

8. Instituto Superior Técnico (IST)

9. Universidade de Lisboa

10. 1049-001 Lisboa

Abstract

Using green chemistry procedures the synthesis of N- and N,N′-alkyl indigo derivatives was undertaken and the effect of the alkyl chain length on the spectral (including color) and photophysical properties of the compounds explored.

Funder

Fundação para a Ciência e a Tecnologia

Programa Operacional Temático Factores de Competitividade

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Reference51 articles.

1. N. Gaboriaud-Kolar , S.Nam and A.-L.Skaltsounis , Progress In The Chemistry of Organic Natural Products , Springer , 2014

2. J. S. Seixas de Melo , in Photochemistry: Volume 45 , The Royal Society of Chemistry , 2018 , vol. 45 , pp. 68–100

3. J. S. Seixas de Melo , in Photochemistry , ed. A. Albini and S. Prodi , RSC , London , 2020 , vol. 47 , pp. 196–216

4. Calculation of Free-Energy Barriers with TD-DFT: A Case Study on Excited-State Proton Transfer in Indigo

5. Excited-State Proton Transfer in Indigo

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