Affiliation:
1. Key Laboratory of Radiopharmaceuticals, College of Chemistry, Beijing Normal University, Beijing 100875, China
Abstract
A Cu-catalyzed asymmetric methylboration of 1,2-dihydroquinolines, 2H-chromenes and 2H-thiochromenes providing boryl products bearing two adjacent chiral centers with excellent selectivities, up to 99 : 1 dr and 99.9% ee, has been realized for the first time.
Funder
Beijing Municipal Natural Science Foundation
National Natural Science Foundation of China
Publisher
Royal Society of Chemistry (RSC)