Arsenic species delay structural ordering during green rust sulfate crystallization from ferrihydrite

Author:

Perez Jeffrey Paulo H.12ORCID,Tobler Dominique J.34ORCID,Freeman Helen M.5ORCID,Brown Andy P.5,Hondow Nicole S.5ORCID,van Genuchten Case M.6ORCID,Benning Liane G.12ORCID

Affiliation:

1. Sec. 3.5 Interface Geochemistry, GFZ German Research Center for Geosciences, Telegrafenberg, 14473 Potsdam, Germany

2. Department of Earth Sciences, Freie Universität Berlin, 12249 Berlin, Germany

3. Nano-Science Center, Department of Chemistry, University of Copenhagen, 2100 Copenhagen, Denmark

4. Department of Plant and Environmental Sciences, University of Copenhagen, 1871 Frederiksberg C, Denmark

5. Leeds Electron Microscopy and Spectroscopy Centre (LEMAS), School of Chemical and Process Engineering, University of Leeds, Leeds LS2 9JT, UK

6. Geological Survey of Denmark and Greenland (GEUS), 1350 Copenhagen, Denmark

Abstract

Arsenic slows the structural ordering and transformation of As-bearing green rust formed from ferrihydrite under anoxic and circum-neutral pH conditions.

Funder

Helmholtz-Gemeinschaft

H2020 Marie Skłodowska-Curie Actions

Engineering and Physical Sciences Research Council

Royal Society of Chemistry

Publisher

Royal Society of Chemistry (RSC)

Subject

General Environmental Science,Materials Science (miscellaneous)

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