Aluminium ion doping mechanism of lithium thiophosphate based solid electrolytes revealed with solid-state NMR-Reference-Cited by-同舟云学术

Aluminium ion doping mechanism of lithium thiophosphate based solid electrolytes revealed with solid-state NMR

Published:2023 Issue:6 Volume:25 Page:4997-5006
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Qu Hongtao¹,Wang Yantao²³,Ju Jiangwei²,van Eck Ernst R. H.¹^ORCID,Cui Guanglei²³^ORCID,Kentgens Arno P. M.¹^ORCID

Affiliation:

1. Magnetic Resonance Research Center, Institute for Molecules and Materials, Radboud University, Heyendaalseweg 135, 6525 AJ Nijmegen, The Netherlands

2. Qingdao Industrial Energy Storage Research Institute, Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao 266101, People's Republic of China

3. School of Future Technology, University of Chinese Academy of Sciences, Beijing 100049, People's Republic of China

Abstract

Doping β-Li3PS4 by adding Al2S3 beyond solubility limit induces highly conductive Li7P3S11 phase and an amorphous fraction improving lithium conductivity.

Funder

China Scholarship Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CP/D2CP04670A

Reference52 articles.

1. Review—Solid Electrolytes in Rechargeable Electrochemical Cells

2. Lithium battery chemistries enabled by solid-state electrolytes

3. Inorganic Solid-State Electrolytes for Lithium Batteries: Mechanisms and Properties Governing Ion Conduction

4. New horizons for inorganic solid state ion conductors

5. Synthesis of a new lithium ionic conductor, thio-LISICON–lithium germanium sulfide system

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