Red to near-infrared piezochromism from AIE-active luminophores: isolated dimers facilitating a wide-range redshift

Author:

Lv Long1,Ye Lijie1,Cao Feng2,Yang Shengchen2,Song Qingbao1,Zou Bo3ORCID,Wang Kai3ORCID,Lv Chunyan4ORCID,Zhang Cheng1ORCID,Zhang Yujian4ORCID

Affiliation:

1. College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, P. R. China

2. Department of Engineering Technology, Huzhou College, Xueshi Rd. No. 1, Huzhou 313000, People's Republic of China

3. State Key Laboratory of Super-hard Materials, Jilin University, Qianjin Street 2699, Changchun, 130012, People's Republic of China

4. Department of Materials Chemistry, Huzhou University, East 2nd Ring Rd. No. 759, Huzhou, 313000, People's Republic of China

Abstract

An AIE-activity architecture with HLCT and highly bright fluorescence was developed and it was the dispersed dimer packing found to be attributable to cholesteryl units. During compression, the dispersed dimers presented a remarkable redshift (157 nm) and high sensitivity (22.1 nm GPa−1).

Funder

National Natural Science Foundation of China

Natural Science Foundation of Zhejiang Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

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