Controlling and correlating the effect of grain size with the mechanical and electrochemical properties of Li7La3Zr2O12solid-state electrolyte-Reference-Cited by-同舟云学术

Controlling and correlating the effect of grain size with the mechanical and electrochemical properties of Li7La3Zr2O12solid-state electrolyte

Published:2017 Issue:40 Volume:5 Page:21491-21504
ISSN:2050-7488
Container-title:J. Mater. Chem. A
language:en
Short-container-title:J. Mater. Chem. A

Author:

Sharafi Asma¹²³⁴^ORCID,Haslam Catherine G.¹²³⁴^ORCID,Kerns Robert D.⁵²³⁴,Wolfenstine Jeff⁶⁷⁸⁴,Sakamoto Jeff¹²³⁴^ORCID

Affiliation:

1. Department of Mechanical Engineering

2. University of Michigan

3. Ann Arbor

4. USA

5. Michigan Center of Materials Characterization

6. RDRL-SED-C

7. Army Research Laboratory

8. Adelphi

Abstract

The strong correlation between LLZO grain size and the Li–LLZO stability as a function of Li plating rate is demonstrated. The increase in grain size reduces the grain boundary area and hence the number of possible failure points leading to an increased maximum tolerable current density.

Funder

Office of Energy Efficiency and Renewable Energy

U.S. Department of Energy

Vehicle Technologies Office

Army Research Laboratory

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/TA/C7TA06790A

Reference68 articles.