Is it ATRP or SET-LRP? part I: Cu0&CuII/PMDETA – mediated reversible – deactivation radical polymerization
Author:
Affiliation:
1. Charles Institute of Dermatology
2. School of Medicine and Medical Science
3. University College Dublin
4. Dublin 4, Ireland
5. Department of Mechanical and Biomedical Engineering
Abstract
The mechanism of Cu0&CuII/PMDETA catalyzed polymerization is attributed to the competition and equilibrium of the traditional ATRP and SET-LRP models.
Funder
Health Research Board
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemical Engineering,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2014/RA/C4RA11477A
Reference21 articles.
1. Reversible-Deactivation Radical Polymerization in the Presence of Metallic Copper. A Critical Assessment of the SARA ATRP and SET-LRP Mechanisms
2. Nitroxide-mediated polymerization
3. Living Radical Polymerization by the RAFT Process – A Third Update
4. Living Free-Radical Polymerization by Reversible Addition−Fragmentation Chain Transfer: The RAFT Process
5. Controlled/"living" radical polymerization. atom transfer radical polymerization in the presence of transition-metal complexes
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