Fabrication of a Cu(<scp>i</scp>)-carboxylate metal–organic framework by reduction of metal nodes for an azide–alkyne “click” reaction-Reference-Cited by-同舟云学术

Fabrication of a Cu(i)-carboxylate metal–organic framework by reduction of metal nodes for an azide–alkyne “click” reaction

Published:2024 Issue:14 Volume:11 Page:4263-4269
ISSN:2052-1553
Container-title:Inorganic Chemistry Frontiers
language:en
Short-container-title:Inorg. Chem. Front.

Author:

Hou Xiaojiao¹²,He Wenxiu¹,Zhai Xu¹^ORCID,Chen Bingbing¹,Fu Yuanlin¹,Zhang Liying¹^ORCID,Chen Junyi³,Fu Yu¹^ORCID

Affiliation:

1. Department of Chemistry, College of Sciences, Northeastern University, Shenyang, 110819, P. R. China

2. Experimental Center, LiaoDong University, Dandong, 118003, P. R. China

3. Engineering Laboratory of Chemical Resources Utilization in South Xinjiang, College of Chemistry and Chemical Engineering, Tarim University, Xinjiang Uygur Autonomous Region, Alaer, 843300, P. R. China

Abstract

A stable Cu(i)-carboxylate MOF is fabricated by ascorbic acid reduction, which breaks HSAB theory and achieves in situ phase transitions. The resultant Cu2H2DOBDC acting as a CuAAC catalyst exhibited superior catalytic performance.

Funder

National Natural Science Foundation of China

State Key Laboratory of Supramolecular Structure and Materials

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/QI/D4QI00922C

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