Nitrogen-doped molecular bowls as electron donors in photoinduced electron transfer reactions

Author:

Stasyuk O. A.12ORCID,Stasyuk A. J.12ORCID,Solà M.1ORCID,Voityuk A. A.1ORCID

Affiliation:

1. Institut de Química Computacional, Departament de Química, Universitat de Girona, C/ Maria Aurèlia Capmany 69, 17003 Girona, Spain

2. Faculty of Chemistry, University of Warsaw, Pasteura 1, 02-093 Warsaw, Poland

Abstract

The propensity of fullerene complex to photoinduced electron transfer is determined by electron-donating properties of the bowl. More extended π-conjugated molecular bowls with nitrogen atom in pentagonal rings promote faster charge separation.

Funder

Departament d'Innovació, Universitats i Empresa, Generalitat de Catalunya

Universitat de Girona

Ministerio de Ciencia e Innovación

Infrastruktura PL-Grid

Publisher

Royal Society of Chemistry (RSC)

Subject

General Engineering,General Materials Science,General Chemistry,Atomic and Molecular Physics, and Optics,Bioengineering

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