Exploration of metal sulfide syntheses and the dissolution process of antimony sulfide in phosphonium-based ionic liquids-Reference-Cited by-同舟云学术

Exploration of metal sulfide syntheses and the dissolution process of antimony sulfide in phosphonium-based ionic liquids

Published:2022 Issue:10 Volume:51 Page:4079-4086
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Grasser Matthias A.¹,Pietsch Tobias¹,Brunner Eike¹^ORCID,Ruck Michael¹²^ORCID

Affiliation:

1. Faculty of Chemistry and Food Chemistry, Technische Universität Dresden, 01062 Dresden, Germany

2. Max Planck Institute for Chemical Physics of Solids, Nöthnitzer Str. 40, 01187 Dresden, Germany

Abstract

Antimony sulfide (Sb2S3) can be dissolved in phosphonium-based ionic liquids (ILs) and re-precipitated in amorphous form. The reaction with a Lewis-acidic imidazolium-based IL results in the formation of quadruple-heterocubane cluster cations.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D1DT04165G

Reference68 articles.

1. Inorganic Synthesis Based on Reactions of Ionic Liquids and Deep Eutectic Solvents

2. Resource-Efficient High-Yield Ionothermal Synthesis of Microcrystalline Cu3–xP

3. Understanding the Chemical Reactivity of Phosphonium-Based Ionic Liquids with Tellurium

4. Ionische Flüssigkeiten und stark eutektische Lösungsmittel in der anorganischen Synthese

5. Halide-Free Synthesis of Hydrochalcogenide Ionic Liquids of the Type [Cation][HE] (E=S, Se, Te)

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