A new aspect of nickel-catalyzed Grignard cross-coupling reactions: selective synthesis, structure, and catalytic behavior of a T-shape three-coordinate nickel(i) chloride bearing a bulky NHC ligand-Reference-Cited by-同舟云学术

A new aspect of nickel-catalyzed Grignard cross-coupling reactions: selective synthesis, structure, and catalytic behavior of a T-shape three-coordinate nickel(i) chloride bearing a bulky NHC ligand

Published:2010 Issue:11 Volume:46 Page:1932-1934
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Miyazaki Satoshi¹²³⁴⁵,Koga Yuji¹²³⁴⁵,Matsumoto Taisuke⁶⁷⁸⁹⁵,Matsubara Kouki¹²³⁴⁵

Affiliation:

1. Department of Chemistry

2. Faculty of Science

3. Fukuoka University

4. Fukuoka 814-0180

5. Japan

6. Analytical Center

7. Institute for Advanced Material Study

8. Kyushu University

9. Fukuoka

Abstract

A novel NHC-nickel(i) chloride was isolated by the reactions of Ni(IPr)₂ with chloroarenes. High catalyst activity of the Ni(i) complex was first demonstrated in Grignard cross-coupling reactions of aryl halides.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2010/CC/B924716E

Reference22 articles.

1. Metal-Catalyzed Cross-Coupling Reactions , ed. A. Meijere and F. Diederich , Wiley-VCH , Weinheim , 2004

2. Modern Organonickel Chemistry , ed. Y. Tamaru , Wiley-VCH , Weinheim , 2005

3. The role of electron transfer and charge transfer in organometallic chemistry

4. Chlorobis(triphenylphosphine)nickel(I) tetrahydrofuran solvate and an unsolvated trigonal phase of chlorotris(triphenylphosphine)nickel(I)

5. Ligand Redox Effects in the Synthesis, Electronic Structure, and Reactivity of an Alkyl−Alkyl Cross-Coupling Catalyst

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