Actinide arene-metalates: 2. A neutral uranium bis(anthracenide) sandwich complex and elucidation of its electronic structure-Reference-Cited by-同舟云学术

Actinide arene-metalates: 2. A neutral uranium bis(anthracenide) sandwich complex and elucidation of its electronic structure

Published:2022 Issue:65 Volume:58 Page:9112-9115
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Murillo Jesse¹,Bhowmick Rina²,Harriman Katie L. M.³,Gomez-Torres Alejandra¹^ORCID,Wright Joshua⁴,Miró Pere²^ORCID,Metta-Magaña Alejandro¹^ORCID,Murugesu Muralee³^ORCID,Vlaisavljevich Bess²^ORCID,Fortier Skye¹^ORCID

Affiliation:

1. Department of Chemistry and Biochemistry, University of Texas at El Paso, El Paso, Texas 79968, USA

2. Department of Chemistry, University of South Dakota, Vermillion, South Dakota 57069, USA

3. Department of Chemistry and Biomolecular Sciences, University of Ottawa, Ottawa, Ontario K1N 6N5, Canada

4. Department of Physics, Illinois Institute of Technology, Chicago, IL, 60616, USA

Abstract

Reaction of [UI2(HMPA)4]I with potassium anthracenide gives the unprecedented arenide-sandwich complex U(η6-C14H10)(η4-C14H10)(HMPA)2. CASSCF calculations indicate the U–C bonding to solely consist of π-interactions.

Funder

U.S. Department of Energy

Natural Sciences and Engineering Research Council of Canada

Welch Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CC/D2CC03238D

Reference25 articles.

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5. Reactivity of (η6-Arene)tricarbonylchromium Complexes toward Additions of Anions, Cations, and Radicals

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