N-Methylcarbamoyl azide: spectroscopy, X-ray structure and decomposition via methylcarbamoyl nitrene-Reference-Cited by-同舟云学术

N-Methylcarbamoyl azide: spectroscopy, X-ray structure and decomposition via methylcarbamoyl nitrene

Published:2017 Issue:9 Volume:4 Page:1839-1848
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Wan Huabin¹²³⁴⁵,Li Hongmin¹²³⁴⁵,Xu Jian¹²³⁴⁵,Wu Zhuang¹²³⁴⁵,Liu Qifan¹²³⁴⁵,Chu Xianxu¹²³⁴⁵,Abe Manabu⁶⁷⁸⁹¹⁰,Bégué Didier¹¹¹²¹³¹⁴,Zeng Xiaoqing¹²³⁴⁵^ORCID

Affiliation:

1. College of Chemistry

2. Chemical Engineering and Materials Science

3. Soochow University

4. 215123 Suzhou

5. P. R. China

6. Department of Chemistry

7. Graduate School of Science

8. Hiroshima University

9. Higashi-Hiroshima

10. Japan

11. Institut des Sciences Analytiques et de Physico-Chimie pour l'Environnement et les Matériaux (IPREM)

12. Université de Pau et des Pays de l'Adour

13. Pau

14. France

Abstract

N-Methylcarbamoyl azide has been characterized and the nitrene intermediate in its Curtius-rearrangement has been observed in two conformations by matrix-isolation IR and EPR spectroscopy.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/QO/C7QO00277G

Reference48 articles.

1. Organic Azides: Syntheses and Applications, ed. S. Bräse and K. Banert, John Wiley & Sons, Chichester, 2010

2. Nitrogenation Strategy for the Synthesis of N-containing Compounds, ed. N. Jiao, Springer, Singapore, 2016

3. Transition Metal-Catalyzed C–H Amination: Scope, Mechanism, and Applications