A photoinduced reaction of perfluoroalkyl halides with 1,3-diarylprop-2-yn-1-ones catalyzed by DABSO-Reference-Cited by-同舟云学术

A photoinduced reaction of perfluoroalkyl halides with 1,3-diarylprop-2-yn-1-ones catalyzed by DABSO

Published:2017 Issue:9 Volume:4 Page:1745-1750
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Li Yuewen¹²³⁴^ORCID,Lu Yiye¹²³⁴^ORCID,Mao Runyu¹²³⁴^ORCID,Li Zhiming¹²³⁴^ORCID,Wu Jie¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry

2. Fudan University

3. Shanghai 200433

4. China

5. State Key Laboratory of Organometallic Chemistry

Abstract

The sulfur dioxide surrogate of DABCO·(SO₂)₂ is used as an efficient catalyst for the cleavage of the perfluoroalkyl-halogen bond under visible-light irradiation. A plausible mechanism supported by theoretical calculations is proposed.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/QO/C7QO00279C

Reference85 articles.

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