Visible-light-induced organocatalytic enantioselective N–H insertion of α-diazoesters enabled by indirect free carbene capture-Reference-Cited by-同舟云学术

Visible-light-induced organocatalytic enantioselective N–H insertion of α-diazoesters enabled by indirect free carbene capture

Published:2023 Issue:4 Volume:14 Page:843-848
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Guo Wengang¹^ORCID,Zhou Ying¹,Xie Hongling¹,Yue Xin¹,Jiang Feng¹,Huang Hai¹^ORCID,Han Zhengyu¹,Sun Jianwei¹²³^ORCID

Affiliation:

1. Advanced Catalysis and Green Manufacturing Collaborative Innovation Center, School of Petrochemical Engineering, Changzhou University, Changzhou, 213164, China

2. Department of Chemistry, The Hong Kong Branch of Chinese National Engineering Research Centre for Tissue Restoration & Reconstruction, The Hong Kong University of Science and Technology (HKUST), Clear Water Bay, Kowloon, Hong Kong SAR, China

3. Shenzhen Research Institute, HKUST, No. 9 Yuexing 1st Rd, Shenzhen 518057, China

Abstract

It has been a long-standing challenge to achieve catalytic asymmetric X–H bond insertion with free carbenes. Herein, an indirect visible-light-promoted asymmetric N–H insertion is disclosed.

Funder

Research Grants Council, University Grants Committee

Innovation and Technology Commission

Changzhou University

Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology Department

Science, Technology and Innovation Commission of Shenzhen Municipality

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D2SC05149D