Aryl tosylates as non-ionic photoacid generators (PAGs): photochemistry and applications in cationic photopolymerizations

Author:

Torti Edoardo12345,Della Giustina Gioia6785,Protti Stefano12345,Merli Daniele2345,Brusatin Giovanna6785,Fagnoni Maurizio12345

Affiliation:

1. Photogreen Lab

2. Department of Chemistry

3. University of Pavia

4. 27100 Pavia

5. Italy

6. Department of Industrial Engineering

7. University of Padova and INSTM

8. 35131 Padova

Abstract

Irradiation of aryl tosylates leads to homolysis of the ArO–S bond and PTSA or p-toluenesulfinic acid was released. The aryl sulfonates tested were then used as non-ionic photoacid generators (PAGs) in hybrid organic/inorganic sol–gel photoresists.

Funder

Fondazione Cariplo

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

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