Effect of tert-butyl substitution on controlling the orientation of TADF emitters in guest–host systems

Author:

Sahay Prakhar1,Crovini Ettore2,Stavrou Kleitos3,Zhang Zhen4,Nguyên Bình Minh1,Wagner Daniel5,Strohriegl Peter5,Bräse Stefan46,Monkman Andrew3ORCID,Zysman-Colman Eli2ORCID,Brütting Wolfgang1ORCID

Affiliation:

1. Experimental Physics IV, Institute of Physics, University of Augsburg, Augsburg, Germany

2. Organic Semiconductor Centre, EaStCHEM School of Chemistry, University of St Andrews, St Andrews, UK

3. Department of Physics, Durham University, Stockton Road, Durham, UK

4. Institute of Organic Chemistry, Karlsruhe Institute of Technology, Karlsruhe, Germany

5. Macromolecular Chemistry, University of Bayreuth, Bayreuth, Germany

6. Institute of Biological and Chemical Systems – Functional Molecular Systems, Karlsruhe Institute of Technology, Eggenstein-Leopoldshafen, Germany

Abstract

We compare how changes in the structure of an acceptor–donor–acceptor TADF emitter decorated with tert-butyl groups affect alignment. The “champion” material is ICzTRZ with tBu-substitution at the distal phenyl rings of the triazine acceptors.

Funder

Deutsche Forschungsgemeinschaft

H2020 Marie Skłodowska-Curie Actions

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

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