Reversal of regioselectivity in reactions of donor–acceptor cyclopropanes with electrophilic olefins-Reference-Cited by-同舟云学术

Reversal of regioselectivity in reactions of donor–acceptor cyclopropanes with electrophilic olefins

Published:2022 Issue:4 Volume:58 Page:509-512
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Turkowska Joanna¹,Durka Jakub¹,Ociepa Michał¹,Gryko Dorota¹^ORCID

Affiliation:

1. Institute of Organic Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, 01-224 Warsaw, Poland

Abstract

Nucleophilicity of Co(i) allows generation of C-radicals from D–A cyclopropanes in a regioselective manner and engaging them in reactions with electrophilic olefins, leading to otherwise difficult to synthesize molecular scaffolds.

Funder

Narodowe Centrum Nauki

Fundacja na rzecz Nauki Polskiej

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CC/D1CC05330B

Reference50 articles.

1. Donor−Acceptor-Substituted Cyclopropane Derivatives and Their Application in Organic Synthesis

2. A New Golden Age for Donor-Acceptor Cyclopropanes

3. Intramolecular donor–acceptor cyclopropane ring-opening cyclizations

4. Carbocycles from donor–acceptor cyclopropanes

5. Synthetic Applications and Methodological Developments of Donor−Acceptor Cyclopropanes and Related Compounds

Cited by 11 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Rh(I)-Catalyzed Regio- and Enantioselective Ring Opening of Vinyl Cyclopropanes;Journal of the American Chemical Society;2024-08-20

2. Intramolecular 1,2-Aroyl Migration in Spiro Donor–Acceptor Cyclopropanes: Formation of 1,4-Naphthoquinones and 1-Naphthols as Ring-Expansion Products;The Journal of Organic Chemistry;2024-04-09

3. Sn(OTf)₂-Catalyzed (3 + 2) Cycloaddition/Sulfur Rearrangement Reaction of Donor–Acceptor Cyclopropanes with Indoline-2-thiones;Organic Letters;2024-02-15

4. Recent advances in ring-opening reactions of 2-substituted donor-acceptor cyclopropanes under metal catalysis;Journal of Organometallic Chemistry;2024-02

5. Vitamin B₁₂ in Photocatalysis – An Underexplored Frontier in Cooperative Catalysis;ChemCatChem;2024-01-15