Insights on hydrogen bond assisted solvent selection in certain acid–base heterogeneous catalysis through acceptor and donor numbers

Author:

Marakatti Vijaykumar S.12345ORCID,Klimeš Jiří678910ORCID,Kasinathan Palraj12345,Sorathia Kesha11121314ORCID,Tew David P.11121314ORCID,Gaigneaux Eric M.12345ORCID

Affiliation:

1. Institute of Condensed Matter and Nanosciences (IMCN)

2. Molecular Chemistry, Solids and Catalysis (MOST)

3. Université catholique de Louvain (UCLouvain)

4. B-1348 Louvain-la-Neuve

5. Belgium

6. Department of Chemical Physics and Optics

7. Faculty of Mathematics and Physics

8. Charles University

9. Prague 121 16

10. Czech Republic

11. Physical and Theoretical Chemistry Laboratory

12. Oxford University

13. Oxford OX1 3QZ

14. UK

Abstract

Acceptor and donor numbers as efficient tools for the selection of solvents in certain acid–base heterogeneous catalysis; role of the hydrogen bond.

Funder

H2020 Marie Skłodowska-Curie Actions

Fonds De La Recherche Scientifique - FNRS

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Reference42 articles.

1. Phenomena Affecting Catalytic Reactions at Solid–Liquid Interfaces

2. Solvent effects in catalysis: rational improvements of catalysts via manipulation of solvent interactions

3. C. Reichardt and T.Welton , Solvent Effects on the Rates of Homogeneous Chemical Reactions, in Solvents and Solvent Effects in Organic Chemistry , 2010 , pp. 165–357

4. Solvent effects on heterogeneous catalysis in the selective hydrogenation of cinnamaldehyde over a conventional Pd/C catalyst

5. L. Gilbert and C.Mercier , Solvent effects in heterogeneous catalysis: Application to the synthesis of fine chemicals, in Studies in Surface Science and Catalysis , ed. M. Guisnet , J. Barbier , J. Barrault , C. Bouchoule , D. Duprez , G. Pérot a and C. Montassier , Elsevier , 1993 , vol. 78 , pp. 51–66

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