In situ generating Cu2O/Cu heterointerfaces on the Cu2O cube surface to enhance interface charge transfer for the Rochow reaction

Author:

Tang Fei12345,Li Jing67895,Zhu Yongxia67895,Ji Yongjun1011125ORCID,Li Huifang67895,Liu Hezhi67895,Wang Xueguang12345ORCID,Zhong Ziyi1314151617ORCID,Su Fabing67895ORCID

Affiliation:

1. State Key Laboratory of Advanced Special Steel

2. School of Materials Science and Engineering

3. Shanghai University

4. Shanghai 200444

5. China

6. State Key Laboratory of Multiphase Complex Systems

7. Institute of Process Engineering

8. Chinese Academy of Sciences

9. Beijing 100190

10. School of Light Industry

11. Beijing Technology and Business University

12. Beijing 100048

13. College of Engineering

14. Guangdong Technion Israel Institute of Technology (GTIIT)

15. Shantou

16. PR China

17. Technion-Israel Institute of Technology (IIT)

Abstract

Cubic Cu/Cu2O with heterointerfaces showed enhanced catalytic performance for the Rochow reaction. The resulting Schottky junction enhanced charge transfer efficiency and contributed to easier cleavage of Si–Si bond along {110} crystal plane.

Funder

National Natural Science Foundation of China

Beijing Technology and Business University

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

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