The acetolysis of 2,2-dimethyl-1-(p-methoxyphenyl)propyl chloride.—The first example of SN2C+-type solvolysis under typical solvolysis conditions in the absence of additives

Author:

Kinoshita Tomomi,Ueda Hiroshi,Takeuchi Ken'ichi

Publisher

Royal Society of Chemistry (RSC)

Reference25 articles.

1. Mechanism of substitution at a saturated carbon atom. Part XXXIX. Nucleophilic substitutions in tertiary alkyl halides by hydroxylic reagents in nitromethane solvent

2. C. K. Ingold , Structure and Mechanism in Organic Chemistry, Cornell Univ. Press, Ithaca, N.Y., 1969, 2nd edn., p. 470;

3. The SN2C+type mechanism can be represented by 'DN+ AN‡ using the IUPAC Commission Recommendation System (IUPAC Commission on Physical Organic Chemistry, Pure Appl. Chem., 1989, 61, 23).

4. Number and structure of solvolysis intermediates. Part 1. A comparison of nucleophilic reactions on in situ generated carbocations with solvolysis reactions for 2,2-dimethyl-1-(p-methoxyphenyl)propyl cation

5. Generation and electrophilic reactions of the 2,2,2-trifluoro-1-(phenylthio)ethyl carbocation

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