Structural confinement-induced highly efficient deep-red emission and negative thermal quenching performance in Mn4+-activated Ca7Mg2Ga6−yAlyO18:Mn4+ phosphors

Author:

Huang Jinmei1,Jiang Pengfei1ORCID,Cheng Zien1,Wang Rong2,Cong Rihong1ORCID,Yang Tao1ORCID

Affiliation:

1. College of Chemistry and Chemical Engineering, Chongqing University, Chongqing 401131, China

2. School of Metallurgy and Materials Engineering, Chongqing University of Science & Technology, Chongqing 401331, P. R. China

Abstract

Extraordinarily high quantum efficiency and abnormal negative thermal quenching were simultaneously achieved in oxide phosphors Ca7Mg2Ga6−yAlyO18:Mn4+ by structurally confining Mn4+-emitters at isolated octahedral sites.

Funder

Natural Science Foundation of Chongqing

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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