Low temperature scalable synthetic approach enabling high bifunctional electrocatalytic performance of NiCo2S4 and CuCo2S4 thiospinels

Author:

Shombe Ginena Bildard12,Razzaque Shumaila3,Khan Malik Dilshad14ORCID,Nyokong Tebello5ORCID,Mashazi Philani56ORCID,Choi Jonghyun7,Bhoyate Sanket7,Gupta Ram K.7,Revaprasadu Neerish1ORCID

Affiliation:

1. Department of Chemistry, University of Zululand, Private Bag X1001, KwaDlangezwa 3880, South Africa

2. Chemistry Department, University of Dar es Salaam, P.O. Box 35061, Dar es Salaam, Tanzania

3. Key Laboratory of Material Chemistry for Energy Conversion and Storage, Ministry of Education, Hubei Key Laboratory of Material Chemistry and Service Failure, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Luoyu Road No. 1037, Wuhan, China

4. Institute of Physical Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, 01-224 Warsaw, Poland

5. Institute for Nanotechnology Innovation, Rhodes University, P.O. Box 94, Makhanda 6140, South Africa

6. Department of Chemistry, Rhodes University, P. O. Box 94, Makhanda 6140, South Africa

7. Department of Chemistry, Pittsburg State University, Pittsburg, KS 66762, USA

Abstract

A scalable solventless approach is employed to prepare NiCo2S4 and CuCo2S4 with bare surface for enhanced supercapacitance and water splitting. The particles exhibit good energy storage and electrocatalytic activity as well as stability.

Funder

National Research Foundation

Horizon 2020

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

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