Copper-catalyzed transformation of alkyl nitriles to N-arylacetamide using diaryliodonium salts

Author:

Sallio Romain12345,Payard Pierre-Adrien678910,Pakulski Paweł12345ORCID,Diachenko Iryna12345ORCID,Fabre Indira678910,Berteina-Raboin Sabine12345ORCID,Colas Cyril12345ORCID,Ciofini Ilaria1112131014ORCID,Grimaud Laurence678910,Gillaizeau Isabelle12345ORCID

Affiliation:

1. Institute of Organic and Analytical Chemistry

2. ICOA UMR 7311 CNRS

3. Université d'Orléans

4. 45100 Orléans

5. France

6. Laboratoire des Biomolécules

7. LBM

8. Département de chimie

9. École normale supérieure

10. PSL University

11. Institute of Chemistry for Health and Life Sciences

12. I-CLeHS

13. Chimie ParisTech

14. CNRS

Abstract

In this study, a simple and efficient method for the copper-catalyzed redox-neutral transformation of alkyl nitriles using eco-friendly diaryliodonium salts and leading to N-arylacetamides was investigated.

Funder

Université d'Orléans

École Normale Supérieure

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

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