The structure and vibrational spectroscopy of cryolite, Na3AlF6

Author:

Parker Stewart F.1234ORCID,Ramirez-Cuesta Anibal J.56789ORCID,Daemen Luke L.56789

Affiliation:

1. ISIS Facility

2. STFC Rutherford Appleton Laboratory

3. Oxon OX11 0QX

4. UK

5. Spallation Neutron Source

6. Neutron Spectroscopy Division

7. Oak Ridge National Laboratory

8. Oak Ridge

9. USA

Abstract

We use a combination of infrared, Raman and inelastic neutron scattering spectroscopies to access all of the modes of cryolite, Na3[AlF6], including those that are forbidden to the optical spectroscopies.

Funder

Science and Technology Facilities Council

U.S. Department of Energy

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Reference47 articles.

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2. J.Thonstad , P.Feller , G. M.Haarberg , J.Hiveš , H.Kvande and Å.Sterten , Aluminium Electrolysis. Fundamentals of the Hall–Héroult Process , Aluminium-Verlag , Dusseldorf, Germany , 3rd edn, 2001

3. Study of NaF−AlF3 Melts by High-Temperature 27Al NMR Spectroscopy:  Comparison with Results from Raman Spectroscopy

4. Structure of High-Temperature NaF−AlF3−Al2O3 Melts: A Multinuclear NMR Study

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