Computational prediction of Au(i)–Pb(ii) bonding in coordination complexes and study of the factors affecting the formation of Au(i)–E(ii) (E = Ge, Sn, Pb) covalent bonds-Reference-Cited by-同舟云学术

Computational prediction of Au(i)–Pb(ii) bonding in coordination complexes and study of the factors affecting the formation of Au(i)–E(ii) (E = Ge, Sn, Pb) covalent bonds

Published:2021 Issue:17 Volume:23 Page:10174-10183
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

López-de-Luzuriaga José M.¹²³⁴⁵^ORCID,Monge Miguel¹²³⁴⁵^ORCID,Olmos M. Elena¹²³⁴⁵^ORCID,Rodríguez-Castillo María¹²³⁴⁵^ORCID,Sorroche Alba¹²³⁴⁵^ORCID

Affiliation:

1. Departamento de Química

2. Universidad de La Rioja

3. Centro de Investigación en Síntesis Química (CISQ)

4. Complejo Científico-Tecnológico

5. 26006-Logroño

Abstract

Computational studies on Au(i)–E(ii) in [R₃PAu–(ECl₃)] (E = Ge, Sn, Pb) model systems indicate the covalent dative nature from the [ECl₃]⁻ metalloligands to Au(i) fragments and predict the existence of Au(i)–Pb(ii) bonds using electron widthdrawing PR₃ ligands.

Funder

Secretaría de Estado de Investigación, Desarrollo e Innovación

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CP/D1CP00325A

Reference34 articles.

1. The Late Start and Amazing Upswing in Gold Chemistry

2. Platinum and Gold Complexes for OLEDs

3. Gold catalysis in organic transformations: A review

4. Gold-Based Medicine: A Paradigm Shift in Anti-Cancer Therapy?

5. The gold–germanium bond in co-ordination compounds of the type (Ph3P)nAuGeCl3with n= 1, 2 or 3

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