Unveiling the role of upper excited electronic states in the photochemistry and laser performance of anti-B18H22

Author:

Cerdán Luis1234ORCID,Francés-Monerris Antonio56789ORCID,Roca-Sanjuán Daniel1011124ORCID,Bould Jonathan131415,Dolanský Jiří131415ORCID,Fuciman Marcel1617181915,Londesborough Michael G. S.131415ORCID

Affiliation:

1. Institute of Physical Chemistry “Rocasolano”

2. Consejo Superior de Investigaciones Científicas (CSIC)

3. Madrid

4. Spain

5. Université de Lorraine and CNRS

6. LPCT

7. F-54000 Nancy

8. France

9. Departament de Química Física

10. Institut de Ciència Molecular

11. Universitat de València

12. 46010 Valencia

13. Institute of Inorganic Chemistry of the Czech Academy of Sciences

14. 250 68 Husinec-Řež

15. Czech Republic

16. Institute of Physics

17. Faculty of Science

18. University of South Bohemia

19. 370 05 České Budějovice

Abstract

Using the first laser borane, anti-B18H22, as a case study, our combined experimental and theoretical approach unravels the photophyscial and photochemical molecular dynamics of a highly efficient luminophore in an excited electronic state.

Funder

Grantová Agentura České Republiky

Ministerio de Ciencia e Innovación

Ministerio de Economía y Competitividad

European Social Fund

European Regional Development Fund

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

Reference56 articles.

1. Boron Science: New Technologies and Applications , 1st edn, ed. N. S. Hosmane , CRC Press , 2012

2. Handbook of Boron Science , ed. N. S. Hosmane , Robert eagling, World Scientific , 2018

3. Boron clusters in luminescent materials

4. Electrochemistry and Photoluminescence of Icosahedral Carboranes, Boranes, Metallacarboranes, and Their Derivatives

5. Distinct Photophysics of the Isomers of B18H22 Explained

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