Manipulating MLCT transition character with ppy-type four-coordinate organoboron skeleton for highly efficient long-wavelength Ir-based phosphors in organic light-emitting diodes

Author:

Feng Zhao1,Yu Yue12ORCID,Yang Xiaolong1ORCID,Sun Yuanhui1ORCID,Zhong Daokun1,Deng Xuming1,Zhou Guijiang1ORCID,Wu Zhaoxin34ORCID

Affiliation:

1. MOE Key Laboratory for Nonequilibrium Synthesis and Modulation of Condensed Matter, Department of Chemistry, School of Chemistry, State Key Laboratory for Mechanical Behavior of Materials, Xi’an Jiaotong University, Xi’an 710049, P. R. China

2. School of Physics and Optoelectronic Engineering, Xidian University, Xi’an 710071, P. R. China

3. Key Laboratory of Photonics Technology for Information, School of Electronic and Information Engineering, Xi’an Jiaotong University, Xi’an 710049, P. R. China

4. Collaborative Innovation Center of Extreme Optics, Shanxi University, Taiyuan 030006, P. R. China

Abstract

Manipulating the MLCT transition character of cyclometalated Ir(iii) complexes with a 2-phenylpyridine-type four-coordinate organoboron skeleton for developing high-performance long-wavelength Ir-based phosphors.

Funder

China Postdoctoral Science Foundation

National Natural Science Foundation of China

Natural Science Foundation of Shaanxi Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

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