Synthesis and investigation of donor–porphyrin–acceptor triads with long-lived photo-induced charge-separate states-Reference-Cited by-同舟云学术

Synthesis and investigation of donor–porphyrin–acceptor triads with long-lived photo-induced charge-separate states

Published:2015 Issue:11 Volume:6 Page:6468-6481
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Kelber Julien B.¹²³⁴⁵^ORCID,Panjwani Naitik A.⁵⁶⁷⁴,Wu Di¹²³⁴,Gómez-Bombarelli Rafael⁸⁹¹⁰¹¹,Lovett Brendon W.¹²¹³¹⁴¹⁵⁴,Morton John J. L.⁵⁶⁷⁴,Anderson Harry L.¹²³⁴^ORCID

Affiliation:

1. Oxford University

2. Chemistry Research Laboratory

3. Oxford

4. UK

5. University College London

6. London Centre for Nanotechnology

7. London

8. Harvard University

9. Department of Chemistry and Chemical Biology

10. Cambridge

11. USA

12. University of St Andrews

13. SUPA

14. School of Physics and Astronomy

15. St Andrews

Abstract

The powerful electron donor tetraalkylphenylenediamine (TAPD) facilitates photo-induced electron transfer, even in a frozen solvent at 10 K, generating a long-lived spin-polarized charge separate state which can be observed by EPR.

Funder

Engineering and Physical Sciences Research Council

Defense Advanced Research Projects Agency

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/SC/C5SC01830G

Reference79 articles.

1. Photoinduced electron transfer in molecular systems: recent developments

2. A Triad Based on an Iridium(III) Bisterpyridine Complex Leading to a Charge-Separated State with a 120-μs Lifetime at Room Temperature