Endohedral Ca@B38: stabilization of a B382−borospherene dianion by metal encapsulation-Reference-Cited by-同舟云学术

Endohedral Ca@B38: stabilization of a B382−borospherene dianion by metal encapsulation

Published:2016 Issue:17 Volume:18 Page:11610-11615
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Chen Qiang¹²³⁴⁵,Li Hai-Ru⁵⁶⁷⁸⁴,Miao Chang-Qing¹²³⁴,Wang Ying-Jin¹²³⁴⁵,Lu Hai-Gang⁵⁶⁷⁸⁴,Mu Yue-Wen⁵⁶⁷⁸⁴,Ren Guang-Ming¹²³⁴,Zhai Hua-Jin⁵⁶⁷⁸⁴,Li Si-Dian⁵⁶⁷⁸⁴

Affiliation:

1. Institute of Materials Science and Department of Chemistry

2. Xinzhou Teachers' University

3. Xinzhou 034000

4. China

5. Nanocluster Laboratory

6. Institute of Molecular Science

7. Shanxi University

8. Taiyuan 030006

Abstract

We present the viability of an endohedralC_sCa@B₃₈which contains aC_sB₃₈²⁻borospherene cage composed of interwoven boron double chains with a σ + π double delocalization bonding pattern, extending the B_n^q(q=n− 40) borospherene family fromn= 39–42 ton= 38.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CP/C5CP06169E

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