Experimental and computational evaluation of the barrier to torsional rotation in a butadiyne-linked porphyrin dimer-Reference-Cited by-同舟云学术

Experimental and computational evaluation of the barrier to torsional rotation in a butadiyne-linked porphyrin dimer

Published:2016 Issue:7 Volume:18 Page:5264-5274
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Peeks Martin D.¹²³⁴⁵,Neuhaus Patrik¹²³⁴⁵,Anderson Harry L.¹²³⁴⁵

Affiliation:

1. Department of Chemistry

2. University of Oxford

3. Chemistry Research Laboratory

4. Oxford

5. UK

Abstract

Temperature-dependent changes in the UV-vis-NIR absorption spectrum of a butadiyne linked porphyrin dimer have been used to determine the height of the energy barrier to torsional rotation.

Funder

European Research Council

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CP/C5CP06167A

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