Diorganotin(iv) 2-pyridyl and 2-pyrimidyl thiolates: synthesis, structures and their utility as molecular precursors for the preparation of tin sulfide nanosheets

Author:

Tyagi Adish1234,Kedarnath G.1234,Wadawale Amey1234,Jain Vimal K.1234,Kumar Mukesh5234,Vishwanadh B.6234

Affiliation:

1. Chemistry Division

2. Bhabha Atomic Research Centre

3. Mumbai-400 085

4. India

5. Solid State Physics Division

6. Materials Science Division

Abstract

Organotin complexes, [R2Sn(2-SC5H4N)2] and [R2SnCl{SC4H(Me-4,6)2N2}] (R = Me, Et) were prepared, characterized and utilized as ssps for the preparation of SnS nanosheets. The direct/indirect band gaps of the latter were evaluated.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

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