Direct formation of 4,5-disubstituted carbazoles via regioselective dilithiation

Author:

Pocock Ian A.12345ORCID,Alotaibi Alya M.12345ORCID,Jagdev Kesar12345ORCID,Prior Connor12345ORCID,Burgess Gregory R.12345,Male Louise12345ORCID,Grainger Richard S.12345ORCID

Affiliation:

1. School of Chemistry

2. University of Birmingham

3. Edgbaston

4. Birmingham B15 2TT

5. UK

Abstract

The simple combination of a bulky TIPS group on nitrogen and C–H activation using nBuLi–TMEDA allows direct functionalization of the hindered bay region of carbazole.

Funder

Prince Sattam bin Abdulaziz University

Engineering and Physical Sciences Research Council

Leverhulme Trust

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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