Effects of silylene ligands on the performance of carbonyl hydrosilylation catalyzed by cobalt phosphine complexes-Reference-Cited by-同舟云学术

Effects of silylene ligands on the performance of carbonyl hydrosilylation catalyzed by cobalt phosphine complexes

Published:2023 Issue:20 Volume:52 Page:6712-6721
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Fan Qingqing¹,Du Xinyu¹,Yang Wenjing¹,Li Qingshuang¹,Huang Wei¹,Sun Hongjian¹^ORCID,Hinz Alexander²^ORCID,Li Xiaoyan¹^ORCID

Affiliation:

1. School of Chemistry and Chemical Engineering, Key Laboratory of Special Functional Aggregated Materials, Ministry of Education, Shandong University, Shanda Nanlu 27, 250100 Jinan, People's Republic of China

2. Karlsruher Institut für Technologie (KIT), Institute for Inorganic Chemistry (AOC), Engesserstr. 15, 76131 Karlsruhe, Germany

Abstract

The effect of silylene ligand on the performance of carbonyl hydrosilylation catalyzed by cobalt complexes is presented. Different mechanisms for the hydrosilylation of aldehydes catalyzed by 1 and 2 were proposed and supported by DFT studies.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Shandong Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D3DT00372H

Reference35 articles.

1. Isolable Silylene Ligands Can Boost Efficiencies and Selectivities in Metal‐Mediated Catalysis

2. Pushing the σ-Donor Strength in Iridium Pincer Complexes: Bis(silylene) and Bis(germylene) Ligands Are Stronger Donors than Bis(phosphorus(III)) Ligands