Experimental and theoretical insights into Co–Ln magnetic exchange and the rare slow-magnetic relaxation behavior of [CoII2Pr]<sup>2+</sup> in a series of linear [CoII2Ln]<sup>2+</sup> complexes-Reference-Cited by-同舟云学术

Experimental and theoretical insights into Co–Ln magnetic exchange and the rare slow-magnetic relaxation behavior of [CoII2Pr]²⁺ in a series of linear [CoII2Ln]²⁺ complexes

Published:2022 Issue:10 Volume:51 Page:4122-4134
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Ahmed Naushad¹^ORCID,Uddin Ansari Kamal¹

Affiliation:

1. Department of Chemistry, Indian Institute of Technology Bombay, Powai, Mumbai-400076, Maharashtra, India

Abstract

A series of near-linear CoII–Ln–CoII complexes are synthesized, and their experimental static and dynamic magnetic behavior is investigated. SMM behavior is observed for Co2Pr, which is rare. The experimental findings are further rationalized using theoretical studies.

Funder

Science and Engineering Research Board

University Grants Commission

Indian Institute of Technology Bombay

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D1DT03573H

Reference75 articles.

1. Single-molecule magnetism of tetrapyrrole lanthanide compounds with sandwich multiple-decker structures