An unusual donor–acceptor system MnIIPc-TCNQ/F4-TCNQ and the properties of the mixed single crystals of metal phthalocyanines with organic acceptor molecules

Author:

Kataeva Olga12345ORCID,Metlushka Kirill12345,Ivshin Kamil12345,Nikitina Kristina12345,Alfonsov Vladimir12345,Vandyukov Alexander12345,Khrizanforov Mikhail12345ORCID,Budnikova Yulia12345ORCID,Sinyashin Oleg12345,Krupskaya Yulia678,Kataev Vladislav678,Büchner Bernd678910,Knupfer Martin678

Affiliation:

1. Arbuzov Institute of Organic and Physical Chemistry

2. FRC Kazan Scientific Center

3. Russian Academy of Sciences

4. 420088 Kazan

5. Russia

6. Institute for Solid State and Materials Research IFW Dresden

7. 01069 Dresden

8. Germany

9. Institut für Feskörper- und Materialphysik

10. Technische Universität Dresden

Abstract

Single crystals of Mn(iii)Pc·2H2O with TCNQ/F4-TCNQ radical anions are stabilized via C–H⋯π interactions. Mn(iii) is in a high spin state.

Funder

Kazan Federal University

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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