Correlating conduction properties with the molecular symmetry: segregation of Z and E isomers in the charge-assisted, halogen-bonded cocrystal [(Z,E)-Me2I2TTF]2Br-Reference-Cited by-同舟云学术

Correlating conduction properties with the molecular symmetry: segregation of Z and E isomers in the charge-assisted, halogen-bonded cocrystal [(Z,E)-Me2I2TTF]2Br

Published:2016 Issue:2 Volume:52 Page:308-311
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Jeannin Olivier¹²³⁴⁵,Canadell Enric⁶⁷⁸,Auban-Senzier Pascale⁹¹⁰¹¹¹²⁵,Fourmigué Marc¹²³⁴⁵

Affiliation:

1. Institut des Sciences Chimiques de Rennes

2. Université Rennes 1

3. UMR CNRS 6226

4. 35042 Rennes

5. France

6. Institut de Ciència de Materials de Barcelona (CSIC)

7. E-08193 Bellaterra

8. Spain

9. Laboratoire de Physique des Solides

10. Université Paris-Sud

11. UMR CNRS 8502

12. 91405 Orsay

Abstract

Co-crystallization of theZandEisomers of Me₂I₂TTF in a mixed-valence bromide salt leads to segregated stacks with two different charge order patterns and associated charge-assisted halogen bonding.

Funder

Generalitat de Catalunya

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CC/C5CC08176A

Reference49 articles.

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4. Organic Conductors: From Charge Density Wave TTF−TCNQ to Superconducting (TMTSF)2PF6

5. Donor–anion interactions at the charge localization and charge ordering transitions of (TMTTF)2AsF6 probed by NEXAFS

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