A novel access to phosphanylidene–phosphorane complexes<i>via</i>P-donor substitution and a detailed bonding analysis-Reference-Cited by-同舟云学术

A novel access to phosphanylidene–phosphorane complexesviaP-donor substitution and a detailed bonding analysis

Published:2023 Issue:38 Volume:52 Page:13781-13786
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Biskup David¹^ORCID,Schnakenburg Gregor¹^ORCID,Boeré René T.²^ORCID,Espinosa Ferao Arturo³^ORCID,Streubel Rainer¹^ORCID

Affiliation:

1. Institut für Anorganische Chemie, Rheinische Friedrich-Wilhelms-Universität Bonn, Gerhard-Domagk-Str. 1, 53121 Bonn, Germany

2. Department of Chemistry and Biochemistry, University of Lethbridge, Lethbridge, AB T1K3M4, Canada

3. Departamento de Química Orgánica, Facultad de Química, Campus Espinardo, Universidad de Murcia, 30100 Murcia, Spain

Abstract

The formation of phosphanylidene–phosphorane complexes is described using a donor replacement reaction starting from anN-methylimidazole-to-phosphinidene complex adduct. The complexes were investigated using electrochemical and computational methods.

Funder

Universidad de Murcia

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D3DT02304D

Reference51 articles.

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4. The borane(III) complexes of (CH3)3PPCF3

5. Darstellung von R3P?P?P(O)(OC2H5)2

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