Intermolecular C–H activation with an Ir-METAMORPhos piano-stool complex – multiple reaction steps at a reactive ligand-Reference-Cited by-同舟云学术

Intermolecular C–H activation with an Ir-METAMORPhos piano-stool complex – multiple reaction steps at a reactive ligand

Published:2015 Issue:82 Volume:51 Page:15200-15203
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Oldenhof S.¹²³⁴⁵,Lutz M.⁶⁷⁸⁵,van der Vlugt J. I.¹²³⁴⁵,Reek J. N. H.¹²³⁴⁵

Affiliation:

1. Homogeneous, Bioinspired & Supramolecular Catalysis

2. van't Hoff Institute for Molecular Sciences

3. University of Amsterdam

4. 1098 XH Amsterdam

5. the Netherlands

6. Crystal and Structural Chemistry

7. Bijvoet Center for Biomolecular Research

8. Utrecht University

Abstract

Reaction of phenylacetylene with an Ir^III(METAMORPhos) complex generates a unique four-membered IrPNC metallacyclic species with an exocyclic CC fragment.

Funder

European Research Council

Nederlandse Organisatie voor Wetenschappelijk Onderzoek

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2015/CC/C5CC05916J

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