Carbonate encapsulation from dissolved atmospheric CO2 into a polyoxovanadate capsule

Abstract

A fully reduced polyoxovanadate compound [Na₆(H₂O)₂₄][H₈VIV15O₃₆(CO₃)]·3N₂H₄·10H₂O (1) with CO₃²⁻ encapsulation in its internal cavity (from dissolved aerial CO₂ in the synthesis reaction mixture) is reported. Compound 1 crystals, on exposure of HCl vapor, excludes carbonate as a CO₂ gas that can be reacted with a Grignard reagent to produce triphenylcarbinol as a major product.