Partial oxidation of step-bound water leads to anomalous pH effects on metal electrode step-edges-Reference-Cited by-同舟云学术

Partial oxidation of step-bound water leads to anomalous pH effects on metal electrode step-edges

Published:2016 Issue:24 Volume:18 Page:16216-16223
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Schwarz Kathleen¹²³⁴,Xu Bingjun⁵⁶⁷⁴,Yan Yushan⁵⁶⁷⁴,Sundararaman Ravishankar⁸⁹¹⁰⁴^ORCID

Affiliation:

1. National Institute of Standards and Technology

2. Materials Measurement Laboratory

3. Gaithersburg

4. USA

5. Department of Chemical and Biomolecular Engineering

6. University of Delaware

7. Newark

8. Joint Center for Artificial Photosynthesis

9. California Institute of Technology

10. Pasadena

Abstract

Loss of electrons caused by adsorption of water on metal electrode step edges explains the anomalous variation of hydrogen underpotential deposition and potential of zero total charge with pH.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CP/C6CP01652A

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